Sounds more like a split hose if the coolant you poured in just poured back out again. I would pop the engine inspection rear cover ( the grille by the boot) off, assuming you have one, get a strong torch so you can see down the back of the engine, and slowly fill the header tank. If it's a pipe you may be able to see which one easily. You may even be able to temporarily fix the split with some jubilee clips and a bit of copper pipe for example.
However as so much coolant has been lost you will need to bleed the system properly now. Which is done at three bleed points, one being on to of the engine area, two under the bonnet.